Figure 1 also shows that the coated mesh has the rough surface. Such hierarchical micro/nanostructure ZnO nanorods array can trap enough air in between substrate surface and water droplet. Therefore, the coated mesh is expected selleck chemicals llc to show superhydrophobicity. The wettability of the as-grown sample was evaluated via the water contact angle (WCA). Figure 3a presents that the WCA on the as-grown sample is about 157 ± 1°, which indicates that the coated mesh is superhydrophobic. Figure 3 The shape of
water and oil droplet on the as-prepared mesh film. (a) Water contact angle about 157 ± 1°, (b) oil contact angle about 0°, and (c) permeating behavior of oil on the mesh film. According to the Wenzel equation [20], the oleophilicity of the oleophilic materials can be enhanced via increasing the roughness of the sample surface. The coated mesh is expected to show superoleophilicity because of the hierarchical micro/nanostructure ZnO nanorods array on the oleophilic stainless steel mesh. Figure 3b shows that the oil contact angle (OCA) on the as-grown film is about 0°, and
the oil droplet will penetrate freely through the coated mesh (Figure 3c). In order to confirm the feasibility of the coated mesh in AICAR nmr practice, as shown in Figure 4, the mixtures of diesel oil and water (volume ratio 3:7) were slowly poured into the test tube; the oil permeated freely through the coated mesh and flowed into the beaker, while the water was repelled on the filter. Figure 4 Concrete experimental process of separation oil and water. (a) Before separation. (b) After separation. Capmatinib in vivo It has been reported that the pore sizes of the original stainless steel mesh are critically important to the wettability of the coated mesh [10]. Figure 5 shows the dependence of WCAs and the OCAs on the pore sizes of the original stainless steel mesh. The WCAs IKBKE on the coated mesh increase with the increase of the pore sizes and have maximum value when the pore size is about 75 μm. Then, the
WCAs became smaller when the pore sizes increase further. The OCAs are always kept at 0° and do not change with the change of the pore sizes. It is generally considered that the larger the WCAs and OCAs distinction, the easier the filtration of water and oil. It can be shown that 75 μm is the optimum pore size for the filtration of water/oil mixtures. Figure 5 Relationship between the pore size of the original stainless steel mesh and the contact angles. Of water and oil on the corresponding coating film. The separation efficiency of the as-grown sample was studied by oil rejection coefficient (R %) [21]. (1) where C 0 is the oil concentration before filtration and C p is the oil concentration after filtration. Hexane, diesel oil, petroleum ether, and gasoline water/oil mixtures were used in the process of experiment. The specific separation efficiency is shown in Figure 6.